Author Topic: Anemopsis californica  (Read 93 times)

Vesp

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Anemopsis californica
« on: March 04, 2010, 04:47:45 AM »
This is an interesting plant. Its major component is elemicin, A very useful chemical. It also lives in places that most useful plants do not.

It also contains methyleugenol, which isn't as useful.

Technical Abstract: Isolation and characterization leaf volatiles in Anemopsis californica (Nutt.) Hook. and Arn. (A. californica) was performed using steam distillation, solid-phase microextraction, and supercritical fluid extraction. Thirty-eight compounds were detected and identified by gas chromatography; elemicin was the major component of the leaf volatiles. While the composition of the leaf volatiles varied with method of extraction, sabinene, 1,8-cineole, piperitone, methyl eugenol, and elemicin were usually present in readily detectable amounts. Greenhouse-reared clones of a wild population of A californica had an identical leaf volatile composition with the parent plants. Steam-distilled oil had antimicrobial properties against 3 (Straphylococcus aureus, Streptococcus pneumoniae, and Geotrichim candidum) of 11 microbial species tested. Some of this bioactivity could be accounted by the oil.

---http://afrsweb.usda.gov/research/publications/publications.htm?seq_no_115=144657

http://plants.usda.gov/java/profile?symbol=ANCA10

http://medplant.nmsu.edu/yerba.html

The only problem is that it is an edangered species, which makes me think that it will be hard to locate -- however, if it has any good concentrations of elemicin, it should be worth it. Does anyone know the concentrations of elemicin it has in it? If not, perhaps the ref I just posted will say?
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Vesp

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Re: Anemopsis californica
« Reply #1 on: March 04, 2010, 04:59:33 AM »
http://molbio.nmsu.edu/Documents/medina.pdf

There it is...

looks like it has 30mgs of elemicin per gram of dried matter. So I guess it has a content of about 3%? That isn't bad. :D
And if I am reading it right... elemicin makes up about 50% of the oil.

It seems like this plant can be bought from various places either as the dried plant material, or from auction places as the living plant.

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shroomedalice

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Re: Anemopsis californica
« Reply #2 on: March 04, 2010, 05:53:22 AM »
why thankyou vesp I have been looking for a good source of elemicin.

I was thinking of synthing it from clove.

Vesp

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Re: Anemopsis californica
« Reply #3 on: March 04, 2010, 05:58:34 AM »
Yeah, but you better check the % and everything, I can't understand it all.

Anyways, it seems like a great little plant -- is it possible to turn allylbenzenznes into PEA's easily? I've never looked into that, but I'd imagine with the double bond it couldn't be that difficult, right? Perhaps it is...
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shroomedalice

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Re: Anemopsis californica
« Reply #4 on: March 04, 2010, 10:15:20 AM »
there are two ways I can think of of the top of my head.

one to isomerise then cleave to aldehyde this is what I would choose as it gives the benzaldehyde which will undergo henry condensation with nitromethane.

two to cleave to the ethyl aldehyde then reductivly aminate. I belive there might be polymerisation problems with some phenethyl aldehydes.

Vesp

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Re: Anemopsis californica
« Reply #5 on: March 04, 2010, 11:50:36 PM »
Thank you for that :)
Seems like a really useful plant, hopefully I can begin to grow some simple for the smell of it.
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thallium

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Re: Anemopsis californica
« Reply #6 on: February 02, 2011, 03:53:12 PM »
It's endangered, your forests are full of Asarum and Hexastylis, go for those instead! ;)

ETA: The roots of the extremely common Asarum canadense contain ~2% essential oil, which in turn contain 20% isoelemicin.
« Last Edit: February 02, 2011, 04:02:40 PM by thallium »

salat

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Re: Anemopsis californica
« Reply #7 on: February 02, 2011, 05:18:00 PM »
The fact that it is endangered is all the more reason to grow some to help preserve it (It's listed in plants for a future's database)

Check out the writeup from Horizon Herbs, He gives some info on where it is wild and it's growing conditions.  It does seem like a weird sort of plant.

http://www.horizonherbs.com/product.asp?specific=818


Dr Duke doesn't have everything and tends to underestimate things but here's what he says.
Plants Containing ELEMICIN

Canarium indicum L. -- Java-Olive, Manila Elemi Essential Oil 8,750 ppm  DUKE1992A 
Myristica fragrans HOUTT. -- Mace, Muskatnussbaum (Ger.), Nutmeg, nogal moscado (Sp.), nuez moscada (Sp.) Seed 3,500 ppm  DUKE1992A 
Daucus carota L. -- Carrot Seed 2,000 ppm  DUKE1992A 
Perilla frutescens (L.) BRITTON -- Perilla Leaf 2,500-3,200 ppm  PC25:2085 
Petroselinum crispum (MILLER) NYMAN EX A. W. HILLL -- Parsley Seed 821 ppm  DUKE1992A 
Acorus calamus L. -- Calamus, Flagroot, Myrtle Flag, Sweet Calamus, Sweetflag, Sweetroot Rhizome 650 ppm  DUKE1992A 
Collinsonia canadensis L. -- Stone Root Plant 18 ppm  DUKE1992A 
Petroselinum crispum (MILLER) NYMAN EX A. W. HILLL -- Parsley Leaf 18 ppm  DUKE1992A

I've been investigating Perilla for a while in general since it supposedly has anti-stress properties.  It's a basil like plant and you can get the oil at chinese grocers and they sell the leaf too.  Maybe I need to plant some this year.  I have the seed, just got more stuff to do than time available.

Salat

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thallium

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Re: Anemopsis californica
« Reply #8 on: February 02, 2011, 05:25:32 PM »
Grow it? Yes.
Wildcraft it? Definitely not!

It's still not much of a source compared to Asarum canadense, which is very common and can be dug up in huge quantities. It also contains more oil (2% when fresh), and it contains the right isomer saving you a step in the synthesis.

Sedit

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Re: Anemopsis californica
« Reply #9 on: February 02, 2011, 06:36:35 PM »
is it possible to turn allylbenzenznes into PEA's easily? I've never looked into that, but I'd imagine with the double bond it couldn't be that difficult, right? Perhaps it is...

There are easier ways then this but just throwing out one of the main means which would be thru anti Markovnikov addition to the double bound. BH3 will add across the bond and can be converted to an amine thru reacting with Chloramine. Any reagent like Borane which will add anti Markovnikov style across the bond would be useful in creating the PEA derivative.
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