6Mono Prpyln Ester Morpines from Pod By Jon @ WD's
this was made the same way as the acetyl ester. it's definitely good
it's a coffe colored tar.
first the poppy straw was ground in a coffee grinder.
extracted with water and vacum filtered.
this evaporated in vacuo and reacted with propionic acid using sodium acetate as catalyst.
in retrospect it would be better to extract the crude extract with hot alcohol and vacum filter until the alcohol gives no more color.
the acid was filtered after 8 hours at 100 C filtered hot under vacum the plant crud was rinsed in hot alsohol and this filtered until no more color this evaporated in vacuo here the acid tends to bump and ceramic chips have to be used as boiling stones.
the crude tar was extraced again with alcohol (hot alcohol) to free it of catalyst. and this evaporated.
bioassy prooves this is definitely potent stuff.
it could be further purified by basing with ammonia collecting the alkaloids that crash out and forming the salt acetic acid would be preferred because you can simply boil off any excess to get a purer form of (i can't say it's heroin) mono propyl ester of morphine.
if one intends to inject this is a must becase the plant tars aren't very good for injection.
when freebasing it's best to salt out the alkaloids some papers indicate that calcium chloride is the best salt to use.
often no precipitate forms unless salt is added.
chloroform or dcm can be used as extraction solvents to recover any bases from the ammonia solution and the filterates.
this stuff really has legs swij's been rocking for the last 8 hours and it feels full blown.
swij decided to quit fucking around and play like the big boys propionic anhydride is easily made in this case calcium proionate 1 mol is mixed with na2s207 sodium pyrosulfate intimately mixed and reacted at 140 C for two hours and distilled at 172C.
results:
propionic anhydride is distilling.
just mix nas207 (sodium pyrosulate) with calcium proionate (any salt will do) even the ammonium salt or the sodium salt it does'nt matter.
heat it to 100-140 C in a grolsh beer bottle for 2 hours.
distill the propionic anhydride swij gets about 50%
the nas2o7 is made by taking a cast iron skillet covering it with a thin layer of sodium hydrogen sulfate (pool ph -) then, heat this directly on a charcol fire, you'll know when finished becasue it gives of wate rand it will no longer appear molten.
so son't fuss with the acid just do it right the first time!!!
pm me if you need help.
the two have to be intimately mixed in a blender for this to work.
propionic acid give 63 yeilds at best.
and that's with a 20+ hour rxn time.
calcium ppropionate is not wated it's a food preservative and it's found at our favorite auction site for around 1$/lb.
oh a few pointers after the water extraction and vac fitration. evaporate on vacuo.
use hot acohol and vacunm filter.
this is the real trade secret:
once evaporated rinse with cool alcohol allow to setlle and filter this, this will concentrate the tar about 10 times more so the morphine content from this is around 20%.
it looks like ipa is the clear winner for getting the plant matter about 100 times more concentrated.
it does'nt keep particulate matter in suspension it has to be done while hot the ipa is best if completely dry.
serturner's method could be applied to the results.
and propionic anhydride gives the very best smack.
this was made like so:
nahso4 is heated over a bed of charcoal in an iron skillet it gets molten and then solidifies.
this is ground up finely this is na2s2o7.
1 mole is mixed finely with 1 mole calcium propinate groud finely (at this point you can smell the anhydride.
heat this between 100-140 C for 1 hour and distill the mess at 172 C you got it.
the contents of the flask can be regrind and distilled further yeilds are very good.
this was made the same way as the acetyl ester. it's definitely good
it's a coffe colored tar.
first the poppy straw was ground in a coffee grinder.
extracted with water and vacum filtered.
this evaporated in vacuo and reacted with propionic acid using sodium acetate as catalyst.
in retrospect it would be better to extract the crude extract with hot alcohol and vacum filter until the alcohol gives no more color.
the acid was filtered after 8 hours at 100 C filtered hot under vacum the plant crud was rinsed in hot alsohol and this filtered until no more color this evaporated in vacuo here the acid tends to bump and ceramic chips have to be used as boiling stones.
the crude tar was extraced again with alcohol (hot alcohol) to free it of catalyst. and this evaporated.
bioassy prooves this is definitely potent stuff.
it could be further purified by basing with ammonia collecting the alkaloids that crash out and forming the salt acetic acid would be preferred because you can simply boil off any excess to get a purer form of (i can't say it's heroin) mono propyl ester of morphine.
if one intends to inject this is a must becase the plant tars aren't very good for injection.
when freebasing it's best to salt out the alkaloids some papers indicate that calcium chloride is the best salt to use.
often no precipitate forms unless salt is added.
chloroform or dcm can be used as extraction solvents to recover any bases from the ammonia solution and the filterates.
this stuff really has legs swij's been rocking for the last 8 hours and it feels full blown.
swij decided to quit fucking around and play like the big boys propionic anhydride is easily made in this case calcium proionate 1 mol is mixed with na2s207 sodium pyrosulfate intimately mixed and reacted at 140 C for two hours and distilled at 172C.
results:
propionic anhydride is distilling.
just mix nas207 (sodium pyrosulate) with calcium proionate (any salt will do) even the ammonium salt or the sodium salt it does'nt matter.
heat it to 100-140 C in a grolsh beer bottle for 2 hours.
distill the propionic anhydride swij gets about 50%
the nas2o7 is made by taking a cast iron skillet covering it with a thin layer of sodium hydrogen sulfate (pool ph -) then, heat this directly on a charcol fire, you'll know when finished becasue it gives of wate rand it will no longer appear molten.
so son't fuss with the acid just do it right the first time!!!
pm me if you need help.
the two have to be intimately mixed in a blender for this to work.
propionic acid give 63 yeilds at best.
and that's with a 20+ hour rxn time.
calcium ppropionate is not wated it's a food preservative and it's found at our favorite auction site for around 1$/lb.
oh a few pointers after the water extraction and vac fitration. evaporate on vacuo.
use hot acohol and vacunm filter.
this is the real trade secret:
once evaporated rinse with cool alcohol allow to setlle and filter this, this will concentrate the tar about 10 times more so the morphine content from this is around 20%.
it looks like ipa is the clear winner for getting the plant matter about 100 times more concentrated.
it does'nt keep particulate matter in suspension it has to be done while hot the ipa is best if completely dry.
serturner's method could be applied to the results.
and propionic anhydride gives the very best smack.
this was made like so:
nahso4 is heated over a bed of charcoal in an iron skillet it gets molten and then solidifies.
this is ground up finely this is na2s2o7.
1 mole is mixed finely with 1 mole calcium propinate groud finely (at this point you can smell the anhydride.
heat this between 100-140 C for 1 hour and distill the mess at 172 C you got it.
the contents of the flask can be regrind and distilled further yeilds are very good.
